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    Formic Acid – Commercial Grade

    Product Specification

    CH2O2

    Formula Weight

     
    Properties
    Molecular formula CH2O2
    Molar mass 46.0254 g/mol
    Appearance Colorless, fuming liquid
    Density 1.22 g/mL, liquid
    Melting point

    8.4°C (47.1°F)

    Structure
    Molecular shape  
    Dipole moment  
    Hazards
    Main hazards Corrosive, irritant, sensitizer.
    NFPA 704  
    Risks Flammable , Causes severe burns.
    Safety Keep locked up and out of the reach of children , Do not breathe gas/fumes/vapor/spray, In case of contact with eyes, rinse immediately with plenty of water and seek medical advice , In case of accident or if you feel unwell seek medical advice immediately.
    Flash point 69°C (156°F)
    Autoignition
    temperature
     
    Related compounds
    Other anions  
    Other cautions  
    Related  
    Related compounds  

    Description

     Formic acid (systematically called methanoic acid) is the simplest carboxylic acid. Its formula is HCOOH or CH2O2. It is an important intermediate in chemical synthesis and occurs naturally, most notably in the venom of bee and ant stings. 

    Uses

    The principal use of formic acid is as a preservative and antibacterial agent in livestock feed. When sprayed on fresh hay or other silage, it arrests certain decay processes and causes the feed to retain its nutritive value longer, and so it is widely used to preserve winter feed for cattle. In the poultry industry, it is sometimes added to feed to kill salmonella bacteria. Other uses:

    It is used to process organic latex (sap) into raw rubber.
    Beekeepers use formic acid as a miticide against the Tracheal (Acarapis woodi) mite and the Varroa mite.
    It is of minor importance in the textile industry and for the tanning of leather.
    Some formate esters are artificial flavorings or perfumes.
    It is the active ingredient in some brands of household limescale remover.
    It is used in laboratories as a solvent modifier for HPLC separations of proteins and peptides, especially when the sample is being prepared for mass spectrometry analysis.
    It is used by clinical pathology laboratories to disinfect prion activity in brain samples
    In synthetic organic chemistry, formic acid is often used as a source of hydride ion. The Eschweiler-Clarke reaction and the Leuckart-Wallach reaction are examples of this application. It is also used as a source of hydrogen in transfer hydrogenation.

    In the laboratory formic acid is also used as source for carbon monoxide, which is set free by the addition of sulfuric acid. Formic acid is also a source for a formal group for example in the formylation of methylaniline to N-methylformanilide in toluene.[2]

    Fuel cells that use modified formic acid are promising.

     

    SAFETY

      The principal danger from formic acid is from skin or eye contact with liquid formic acid or with the concentrated vapors. Any of these exposure routes can cause severe chemical burns, and eye exposure can result in permanent eye damage. Inhaled vapors may similarly cause irritation or burns in the respiratory tract. Since carbon monoxide may also be present in formic acid vapors, care should be taken wherever large quantities of formic acid fumes are present. The US OSHA Permissible Exposure Level (PEL) of formic acid vapor in the work environment is 5 parts per million parts of air (ppm).

    Formic acid is readily metabolized and eliminated by body. Nonetheless, it has specific toxic effects; the formic acid and formaldehyde produced as metabolites of methanol are responsible for the optic nerve damage causing blindness seen in methanol poisoning.[3] Some chronic effects of formic acid exposure have been documented. Some animal experiments have demonstrated it to be a mutagen, and chronic exposure may cause liver or kidney damage. Another possibility with chronic exposure is development of a skin allergy that manifests upon re-exposure to the chemical.

    The hazards of solutions of formic acid depend on the concentration. The following table lists the EU classification of formic acid solutions:

    Concentration (weight percent) Classification R-Phrases
    2%–10% Irritant (Xi) R36/38
    10%–90% Corrosive (C) R34
    >90% Corrosive (C) R35

    International Chemical Safety Card

     

     

       
     

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